Ammonia as a source of Hydrogen for future cars

Synthesis of Ammonia is one of the  remarkable achievements of Chemical engineering in forties .It is a precursor for Urea, the fertilizer  that  brought about ‘Green revolution’ in agriculture industry and helped to achieve record food production all over the world. It was a milestone in modern chemistry to synthesis a molecule containing I atom of Nitrogen and 3 atoms of Hydrogen, represented by NH3 called Ammonia. The HeberBosch process for the production of Ammonia is a well established mature, commercial technology.

The process uses a Hydrocarbon source such as Naphtha or Natural gas as the feed stock to generate a synthesis gas composed of Hydrogen and Carbondioxide.The gas mixture is separated into carbon dioxide and Hydrogen using PSA (pressure swing adsorption ) technology. The resulting Hydrogen is used to combine with Nitrogen to synthesize Ammonia.

The chemical reaction can be represented by the following equation.

N2 + 3H2 ———- 2 NH3

The above reaction takes place at a pressure of 100-200 bars and temperature of 300-500C in presence of  catalysts. It is an exothermic (heat releasing) reaction and the catalyst bed is cooled and maintained at 400C to be efficient.But this process of Hydrogen generation using Hydrocarbon emits greenhouse gases. Alternatively, Hydrogen can be generated using different methods using renewable energy sources using water electrolysis. Such process may be used in the future for this application.

Nitrogen is derived from atmospheric air. The air we breathe has about 79% of Nitrogen and 21% Oxygen. But these two gases can be separated by liquefying the air by cryogenic process and distilling them into two fractions. Alternatively, they can separated using pressure swing adsorption or membrane separation process, utilizing their density differences. In either way, Nitrogen can be separated from atmospheric air. By combining the above Hydrogen and Nitrogen, it is possible to synthesis Ammonia on a commercial-scale.

The ammonia can be easily split into Hydrogen and Nitrogen by passing Ammonia through a bed of Nickel catalyst at 200-400C as and when required to generate on site Hydrogen. This Hydrogen can be used for power generation or to run our cars using PEM Fuelcell.As we have seen previously, we are now looking for various sources of Hydrogen, and Ammonia is one of the promising sources for couple of reasons. The process and technology of Ammonia production, transportation and usage is well documented and has been practiced for few decades. It does not emit  greenhouse gases.Liquified Ammonia has been widely used in air-conditioning and refrigeration systems. Ammonia can be easily metered into any system directly from the cylinder.

It is easier to use Ammonia directly into a convention internal combustion engines in place of Gasoline and this technology has already been practiced in 1880. Ammonia is pungent and any leakage can be easily identified. The advantage of using Ammonia as a fuel in cars, it does not emit any smoke  but only water vapour.It can be admixed with Gasoline or used as 100% anhydrous Ammonia. It also helps in reduction of NO2 emission, especially is diesel engines.

Ammonia has a great potential as a source of future fuel provided the sources of Hydrogen comes from water using renewable technologies or by photo electrolysis using direct sunlight.

Why should you choose Photovoltaic Hydrogen over Photovoltaic battery?

 Photovoltaic (PV) power is becoming popular worldwide as an alternative to grid power for various reasons. It gives an energy independence and freedom, it helps reduce greenhouse gas emission and combat global warming, it helps people taking advantage of various Government subsidies and incentives, and it also generates some revenue by selling surplus power back to the grid. At the end of the period you own the system and claim depreciation and some tax benefits. All these compelling factors may motivate people to opt for PV solar power. But you should also do some math and make a cost benefit analysis to choose a right system for you.

When there is a good sunshine day after day and throughout the year, PV solar is good proposition and can be really rewarding. Unfortunately that is not the reality. There may be many cloudy, rainy and fogging days in a year and your PV solar capacity may be overestimated or underestimated. You know the real data only after one or two years of life experience. It is a long-term financial and ethical decision one has to make and the decision should be absolutely right. You can make such a decision by carefully examining all the factors, not just by looking at the first cost but looking at operating and maintenance costs and all the costs and benefits associated with them.

Storage batteries are inevitable in PV solar systems, especially for grid independent systems. Even with grid connected PV solar system the design and installation of a correct battery bank, controllers and rectifier are important issues. In this article we will discuss about grid independent system because many developing countries in Africa and Asia do not have 24×7 uninterrupted grid power supplies. Many people living in islands have to manage their own power by using diesel generators. This is the stark reality.

Let us assume that you design a system assuming a daily average power consumption of 25,000 kwhrs/day, which is suitable even for a medium size family in US. We made an optimum design study between two  systems; first  containing PV solar,battery,controller for grid independent power supply; and second  system with PV solar, battery, water Electrolyzer,Hydrogen storage  and PEM Fuel cell and a rectifier for grid independent system,  based on the same power consumption of 25,000kwhrs/day. You can clearly see the difference between the two systems by the following data.This financial analysis was made assuming there is no Government subsidies and incentives.

Grid independent system with battery storage for 25,000kwhrs/day power:

Total NPV (net present value):$ 342,926

Levelized cost of energy: $2.94/kwhrs

Operating cost/yr: $22,764

Grid independent system with Hydrogen storage for 25,000kwhrs/day power:

Total NPV (net present value): $ 169,325

Levelized cost of energy : $ 1.452/kwhrs

Operating cost/yr: 8,330

The number of batteries required in the first case is 17 numbers. In the second case, number of batteries required is only 2.Obviously,  the levelized cost of power using  PV Hydrogen (storage) is less than 50% of the power generated using PV battery (storage) for the same energy consumption of 25,000kwhrs/day. The operating cost is only one-third for PV Hydrogen system compared to battery system. Batteries are indispensable in any renewable energy system but reducing their  numbers to the lowest level is important, when the life of the system varies from 25 years to 40 years. The numbers and the cost of batteries and their maintenance cost  will make all the difference.

 

Why PV solar is still considered expensive?

Photovoltaic  solar industry has started expanding in recent years in US and Europe and the rest of the world also started following. Still solar energy is considered expensive in many parts of the world for various reasons. In most of these countries, energy is predominantly managed by Governments with age-old technologies and transmission systems. Coal is still the major fuel used for power generation and distribution and their infrastructures are old and inefficient. Transmission losses, power pilfering, subsidized power tariffs and even free power for farmers, are some of the issues that compounds the problems. Energy and water are considered more of social issues rather than business issues. For example in India, frequent power failures are common  and sometimes people do not have power even up to 8 to 12 hours  a day, especially  in country sides. Standby diesel generators are integral part of an industry or business. The heavily subsidized power supply by Government from coal-fired power plants is  underrated. The average power tariff in India is still less than $0.07/kwhr.But the reality is they will be using diesel generated power for equal several hours in a day  and the cost of diesel power varies from  $0.24 up to $0.36/kwhrs, almost in par with solar power. The average power cost will amount to $0.18 to $0.20 /kwhrs.

Any slight increase  in oil price will have a dramatic effect in energy cost in India and their balance of payment situation.Governments are in a precarious situation and they have to make a balancing act between subsidizing the energy cost and winning the elections. They often subsidize the power resulting in heavy revenue losses for Government run electricity boards. Most of the electricity boards in India are in red. People are used to low power tariffs for several decades and any increase in the tariff will make the Government unpopular. Greenhouse effect and global warming are secondary issues. With an average economic growth rate at 7% year after year, their energy requirements have gone up substantially. They may need several hundred thousands of MW power in the next 5 to 10 years. They have opened up energy sector to private only in recent years.

Renewable energy industry is relatively new and there are very few large commercial-scale solar and wind power plants in India. Majority of residents and businesses cannot afford high cost of PV solar installation. Even if they install, there is no ‘power- in tariff’ mechanism by Government where consumers can export surplus energy at a higher tariff to the grid. With current power failures lasting 8-12 hours/day, such mechanisms will have no value. The situation is the same in many Asian countries.

The solar panel costs are high due to lack of local production of silicon wafers, batteries and inverters and most of them are still imported. State electricity boards do not have funds to buy power at higher tariffs. Import duties and taxes on imported components are still high making renewable industries uncompetitive against cheap coal-fired,  subsidized power cost of $0.07/kwhrs .India requires massive investment on renewable energy industries. But most of the power projects which are under planning stage or under implementation are based on either coal or oil or LNG.There is no sign that India will soon become a major player in renewable energy.

In PV solar projects, the cost of storage batteries are higher than the solar panel during the life cycle of 25 years. If the life of a battery is 8 years then you will need 3 batteries during the life cycle. For example, if you use 100 watts solar panel with a life span of 20 years, the initial cost of solar panel may be $300 which will generate an average power of 140 watt.hrs /day. If you plan to store 5 days energy using a battery, you will enquire 5x 140= 700 watt.hrs battery, costing about $175.If you have to replace batteries 3 times during the life span of 20 years then the cost of battery is 3×175= $525.You have to add operation and maintenance cost, in addition to it. Therefore, your investment on batteries is 1.75 times more than solar panels. This cost will substantially add up to your energy cost.

In most of the Asian countries where they cannot export surplus power to the grid, they have to rely only on batteries. This high cost of stored energy is not remunerative because they cannot export this surplus to the grid at a higher tariff. This situation is not likely to change at least in the short-term.

Solar energy storage with Battery or Hydrogen?

Renewable energy industry has slowly but steadily started expanding in many parts of the world in spite of  high cost of investment and high  cost of energy. Countries like US, Germany and China are now investing on large-scale solar and wind technologies, opening new avenues for investments and employment opportunities. Many of these technologies will undergo several changes over a time before it can completely substitute fossil fuels. How long this process will take will depend upon number of factors; but the single biggest driving force will be ‘the issue global warming and its consequences” and also on uncertainties over oil reserves in the world. Nothing dramatic will happen in the near future except that the concept of alternative source of energy will expand rapidly. It is also an opportunity to discover new forms of fuels, power generation and distribution methods.

The concept of solar energy is now well-recognized as an alternative source of energy because, it is abundantly available, it is clean, generates no pollution and it is silent. The major raw materials such as Silica  and Gallium Arsenide  are  also available but some of the rare earth materials used in PV industries and batteries  are available only in certain parts of the world.  China is endowed with many such rare earth resources. For example, Lithium has limited resources and now bulk of it is produced from natural brines similar to the one at Atacama deserts in South America. It is also available in the form of minerals and ores which many countries are now trying to exploit commercially.

The storage of energy from  solar and wind is  done using deep cycle batteries, most of which are Lead-acid batteries. Bulk of the used Lead acid batteries are recycled but the demand for such batteries keeps increasing. As I mentioned in my previous articles, the sheer weight of these batteries, space required to install them, capacity use, capacity constraints, regular need for  maintenance and life cycle are some of the issues that are critical for renewable industries. In deep cycle batteries, discharging stored energy below certain levels dramatically reduces the life span. Hot climate conditions have certain impacts on maintaining such batteries.Life of a battery is critical because when you calculate the cost of energy over the life cycle of 25 years,the several replacements of battaries and their cost will have a dramatic effect on the cost of energy.

Batteries are indispensable tools in energy industries but their usage can be minimized  to a great extent by using Hydrogen as a storage medium. Let us analyze a simple example of a PV solar system for power generation. We made a computer simulation on three  different  scenario for a PV solar system for a small residence with power consumption at 15,500kwhrs/day. First simulation was based on PV solar, direct grid connect, without  storage batteries but connected directly to the grid, assuming the grid power tariff  is at $0.10/kwhrs and sale to grid tariff at $ 0.30/kwhrs.The second simulation was based on grid independent system  using battery  storage for 8 hrs autonomy. The third simulation is also grid independent, but solar power is connected to an Electrolyzer to generate Hydrogen and store it in a tank. We used a small capacity battery, less than twenty percent  of the capacity used in the earlier case and a Hydrogen storage with Fuel cell along with an inverter. The stored Hydrogen was used to generate power to meet the requirement of the residence, instead of supplying power directly from the battery. The cost of energy using direct grid connect was the lowest $$0.33/kwhrs, while Grid independent with battery storage ,the cost of power was $1,20/kwhrs.In third  scenario with Hydrogen and Fuel cell the cost of power was $ 1.90/kwhrs, but there was surplus Hydrogen in the storage tank. With Hydrogen as a storage medium, the cost of power is high due to initial investment but it is maintenance free and ideal for remote locations.

The Hydrogen and Fuel cell solution though expensive, has a several advantages. The power generated by PV solar is stored in the form of Hydrogen instead of storing in batteries. A single battery is used to keep up a steady current to Electrolyzer but bulk of the energy is stored in the form of Hydrogen. Another advantage with this system is that stored Hydrogen can also be used as a fuel for residential heating as well as to fuel your car.

How to power your home and fuel your car with Hydrogen?

There is a general opinion that Hydrogen is dangerous or explosive; people are often reminded of Hindenburg accident or Hydrogen bombs. Hydrogen is as safe as Gasoline or Butane gas. It should be handled with care like any combustible material. We have used Hydrogen in industries for so many decades and transported by pipelines across thousands of kilometers; the methods and procedures of handling Hydrogen is well established. It is a very light, colorless and odorless gas and it can easily escape into the atmosphere. Hydrogenation of vegetable oils for production of certain Margarines is one the classical industrial examples for Hydrogen usage. When 100m3 Hydrogen is compressed to 10,000psi pressure, it is reduced to just 0.163 m3 by vlume.That is how the Hydrogen storage space is reduced in passenger cars. This volume of gas can give a mileage of 652 miles, using Fuel cell power. The only emission is just pure water vapor! No noise, no smoke and it is entirely a new experience driving a Hydrogen Fuel cell car.

Powering your home with Hydrogen or fuelling your Fuel cell car is not very difficult. It is expensive compared to grid power for two simple reasons. Grid power is generated by power generation companies somewhere else using coal, oil or gas and transmitted across to millions of people.Therefore,  the  investment on power generation is shared by millions of people through their monthly energy bills. When you use the grid power, you do not pay any large sum except, a small deposit of few hundred dollars towards connection fee, and you pay your bills based on your monthly electricity usage.

But when you try to generate your own power using a solar panel or Fuel cell then you have to make an investment fully upfront. Of course, your bank can help you with the finance for the system. However, when you calculate the energy cost over the life period of 25 years then you can clearly see the value of such investment. The grid power cost will only increase and never decrease while your generation cost will decrease as the time passes. The future energy cost is likely to increase substantially due to various factors. You can export surplus power to the grid and your payback time will be reduced as the energy cost increases.

The first step in powering your home is to calculate your power requirements accurately in terms of watt.hrs.How many appliances you will be using  and how many hours you will using each of these appliances per day. Suppose you estimate 15,000 watt.hrs/day or 15kwhrs/day of power, and then a small Fuel cell consuming 1 Kg/day of Hydrogen or 30 kgs/month of Hydrogen will be sufficient to meet your power demand. Similarly you can calculate the amount of Hydrogen you will be using as a fuel for your Fuel cell car. For example, if you will be  driving your Fuel cell car for 1000 miles per month, then  your Hydrogen requirement will be about 14 kgs/month. Your Hydrogen requirement per month for both power and car together will be 44 kgs only.

Your total  power need to generate the above Hydrogen will be 2464 kwhrs/month costing less than $250 per month for both power and fuel. Of course you need to calculate other fixed costs on the investment. You can export your solar power at a higher tariff to the Government and import your power requirement from the grid during off-peak season at a lower tariff and generate Hydrogen and store it. You can generate your power as and when you need, and you are in complete control of your situation, even if there is a blackout due to grid failure!

Hydrogen is cheaper than Gasoline and Diesel

There is a general opinion that Hydrogen is now very expensive compared to Gasoline and Diesel. It depends on how you generate Hydrogen. We have used Gasoline and Diesel for several decades and real cost of crude oil is much lower than what we are paying for Gasoline and diesel at the service stations. Crude oil is formed naturally and all the cost involved is for pumping, transportation and refining. The cost of energy spent on transportation and refining is also comparatively low. It is the geopolitical situation in the world, supply demand gap, Government taxes and levies, inventory levels, financial market and distributors play a key role in fixing the price of these fuels.

Hydrogen can be generated from tap water without involving fossil fuels at all. But Governments are spending on research and development of Hydrogen generation using fossil fuels such as natural gas and coal. It is understandable that these sources are suitable for bulk production of Hydrogen on an industrial scale. We will also be able to use existing fossil fuel infrastructure to the most extent. But the flip side of this approach is Hydrogen generated by this route is still not pure enough to meet Fuel cell requirements. This Hydrogen may be suitable for Hydrogen combustion engines. Why they are not suitable? For example, Hydrogen is generated from natural gas by steam reforming,Syngas is generated as an intermediary product which is a mixture of Hydrogen and Carbon monoxide; but also other impurities present in natural gas such Sulfur,Phosphorus and Mercaptans etc.Natural gas has to be purified to remove all these impurities before it can be subject to steam reformation. In spite of an elaborate purification methods adopted, Fuel cell suppliers are reluctant to guarantee the life of their Fuelcell.The Fuel cell uses expensive Platinum as a catalyst which can be readily poisoned by the presence of impurities in Hydrogen, produced from natural gas. This is one of the main reasons why Hydrogen becomes expensive by this route. Industries can pay high cost for this Hydrogen, but ordinary citizens cannot afford to pay.

Hydrogen can be generated directly from tap water by simply electrolyzing it using a Direct current such as solar and wind. If we use grid power, it requires about 68kwhrs of electricity, costing about $3.40 per Kg of Hydrogen. Assuming Hydrogen will cost about $5 per kg after compression and storage, it is still worth the cost. This Hydrogen will give a mileage of 73.4 miles/kg using Fuel cell car. This is equal to 3.67 Gallons of gasoline costing about $13.76, at the rate of $3.75 per gallon. It is very clear that hydrogen is cheaper than gasoline or diesel. At the current price,Gasoline  costs 275% more than Hydrogen gas.

By converting existing coal and oil based power plants into IGCC, Integrated Gasification and Combined Cycle plants, Government can cut the current emission levels of greenhouse gases, and at the same time supply electricity at the prevailing rates. We do not have to import oil or gas. Government should fund conversion of coal and oil-fired power plants into IGCC plants and create Hydrogen infrastructure, by producing more Hydrogen Fuel cell cars and Hydrogen service stations. By adopting this policy, US Government can bring down the prices of crude oil in the international market which will help cut the prices of all other petrochemical products like fertilizers, plastics, drugs and cosmetics. The crux of the issue is to divert petroleum products from fuel use to other uses. At the same time Governments can reduce their greenhouse emissions to the level demanded by scientists. By reducing the cost of solar panels to less than $.100 per watt, Renewable Hydrogen will become a commercial reality and that will be the end of fossil fuels.

How to increase energy efficiency and reduce carbon foot print?

There are many ways to increase the energy efficiency of an existing system which also helps invariably to cut your carbon footprint. The inefficiencies breed pollution. Such inefficiencies can emanate from power generation methods or from power distribution methods. Energy cannot be stored but has to be used. That is one of the main reasons why the power companies look for large consumers and offer them the lowest tariff. Some industries like Caustic soda plants and Aluminum smelters, consume large power.

If you are using power from the grid then you can discuss with your service provider and check whether you can switch over to green power. The tariff may be slightly higher than a standard tariff but certainly helps you to reduce your carbon footprint. Some service providers show your carbon foot print by way a chart in their monthly energy bill. Most of the energy providers supply green power such as solar and wind as part of their energy mix to make sure that they don’t lose customers who may insist on green power.

You can check various power tariffs in your place such a peak tariff and off-peak tariffs and you will be surprised at the difference. The peak tariff is when everybody use power , normally 9am to 5pm.The usage of air-conditioners  during peak hours in  tropical countries is high They can use rooftop  solar panels with batteries and inverters because many counties in Asia do not have  feed-in tariff method by which you can export your surplus solar power to the grid. Moreover they do not have a choice in selecting a service provider because power generation and distribution are mostly runs by Governments or by very few service providers. The best method for such users is to store the solar energy in batteries and use them when they want. Even consumers who use grid power can store electricity during off-peak period using batteries and then use them during peak period using an inverter. This is an ideal solution for Asian countries where the power outage is frequent and unexpected.

The best method will be to use an Electrolyzer to generate Hydrogen using off-peak power and tape water and store them under pressure. You can generate your own electricity using small Fuel cell .This electricity can be a Direct current that can be readily connected to a host of Direct current operated appliances including your air-conditioners and refrigerators. If your electricity load is relatively high then you can integrate both solar panels and grid power in such a way that you can store enough electricity by way of Hydrogen or in a battery and use them during peak period. By this method you can be certain of an uninterrupted power supply and at the same time a reasonable power tariff. You can reduce your carbon foot print substantially   by utilizing solar power with Hydrogen storage.

You can choose energy-efficient appliances by looking at their star ratings.A star rating of 6 and above is considered very energy-efficient. You can choose LED bulbs for lighting and I would suggest using Direct current for LED bulbs directly from Fuel cell or battery and not from grid supply using an inverter. You can also check the type of refrigerants used in air conditioners and Refrigerators and their star ratings. If you have a roof top solar panel as part of electricity supply then I will recommend to use Direct current operated Air-conditioners and regfigerators.When you choose these appliances you can look for the type of motor, compressor and fans  used, because these are the main parts that use electricity. An energy-efficient motor and the type of compressor used are critical components in determining the capacity, airflow and noise levels. The energy ratings are based on these factors only.

You can save energy and cut your carbon footprint in every step of the way if you are keen to do it. The most important factor in achieving energy efficiency is an understanding of your contribution to the environment and the prudence with which you can achieve these goals.

The solar,wind and water- three keys for energy independance

Renewable Hydrogen is the key that can offer us energy independence in the twenty-first century. Fossil fuel usage will still continue for some more time because the world has already invested massively on fossil fuel infrastructures. The stacks are too high for them to switch over to renewable over night. It is the Mother Nature who provided us coal, oil and gas all these years using her manufacturing process under the earth over millions of years. But we human beings exceeded her tolerance limit by emitting greenhouse emission by our rapid growth in population and industrialisation.We failed to discover an alternate fuel in time and continued with an age-old technology with all its inefficiencies. Inefficiencies breed pollution. We were keen to use the heat of combustion by burning a fossil fuel to generate electricity or drive our cars, but paid no attention to the gases released during such combustion. We learnt Thermodynamics and the relationship between heat and work, but failed to understand the consequences of gases of combustion and its impact on our environment.

There are two issues involved in burning a fossil fuel to generate electricity. The heat of combustion is an exothermic reaction and we get a certain amount of heat. Then we convert this heat energy into electrical energy and the overall efficiency of such conversion is about thirty-five percent. Only thirty-five percent of the heat input energy becomes electrical energy and the remaining sixty-five percent heat along with gases of combustion are released into atmosphere. Of course part of this heat is recovered in a commercial plant, but the bulk of heat is released into the atmosphere as greenhouse gases. We failed to understand the potential of Hydrogen even though we used Hydrocarbon for several decades. We even discovered Urea, the fertilizer that caused ‘green revolution’ in agriculture, using the same Hydrogen present in the Hydrocarbon feedstock. It is time for us to make best use of a fossil fuel to its most potential when we burn each kilogram of fuel. We should burn coal not just with air but also with steam so that we can generate Hydrogen rich gas that can run a gas turbine in a combined cycle or run our cars on roads. Such a conversion will lead to a substantial increase in energy efficiency as well as in greenhouse gas emission reduction. Governments in industrialized countries should make it a mandatory to convert all their power plants to syngas generation as described above. They should also discourage new plants using fossil fuels with punitive power tariffs and encourage renewable energy projects with higher tariffs. Governments can also impose similar tariffs for transportation depending upon the fuel used such as fossil fuel or Hydrogen.

Governments should encourage renewable energy projects such as solar and wind   to generate Hydrogen from water as centralized power plants and distribute DC (direct current) by rural electrification. If the country side is electrified using this system then, agriculture, business and industries can thrive in rural areas. Direct current (DC) distribution net work can be installed in rural areas and encourage people to use energy-efficient appliances such as Direct current air-conditioners with energy star ratings and tariffs. Governments can bring about these changes by adopting a ‘carrot and stick ‘policy to encourage renewable and discourage fossil fuels.

Solar energy is the key from which all other forms of energy emanate such as wind, geothermal and ocean thermal energy conversion system.  It is of paramount importance to increase the efficiency of renewable systems and improve energy efficiencies of appliances we use. It is simpler to use LED bulbs using a Direct current generated by Renewable Hydrogen. It is once again the Mother Nature that can come to the rescue of human beings through solar, wind and water to generate clean energy for the twenty-first century.

Energy generation and distribution is no longer a business or revenue issue but a moral and ethical issue for Governments. It is only people who can bring about such sweeping changes by electing the right Government who can care for the environment. The future generation will judge us only based on what kind of environment we leave them behind.

Hydrogen from Coal

Coal is an important fuel that helped industrial revolution. It is still a main fuel for power generation in many parts of the world. It is also an important raw material for number of chemicals and they directly compete with Hydrocarbons such as Naptha.It is abundantly available and it is cheap. We are still able to generate electricity at 5 cents per kwhr using coal. But, now we are entering into a new phase of energy generation and distribution, due to changing environmental and climatic issues of the twenty-first century. We need completely a new fuel to address these issues; a fuel that has a higher heat content, which can generate more power per unit value of fuel, and yet, generates no pollution. It is a challenging job and the world is gearing up to meet these challenges. They affect the world because any issues about energy impacts each and every one of us. Many industrialized countries around the world are reluctant to sign an agreement that compels them to cut their greenhouse emission to an acceptable level set by UN panel of scientists.

Governments such as US, China and India are reluctant to sign such an agreement because their economy and growth depends upon cheap energy, made from coal. Such an agreement will be detrimental to their progress, and the leaders of these nations are not ready to sign such an agreement. They also understand that world cannot afford to continue to use coal as they have used in the past. It is simply unsustainable. It is a precarious situation and they need to carefully plan their path forward. On one hand, they need to keep up their industrial and economic growth, and although they need to cut their emissions and save the world, from catastrophic consequences of global warming.

A simple analysis of the fuel will show that Hydrogen is a potential energy source for the future. It has energy content at least five times more than a coal for a unit value. Coal has an average heat content of 5000 kcal /kg while Hydrogen has an average heat content of 39,000 kcal/kg. Coal has a number of impurities such as ash, sulfur, phosphorous, other than carbon. Burning coal will emit greenhouse gases with toxic fumes that have to be removed. Therefore, these industrialized countries are now looking ways to generate Hydrogen from coal; that too at a cost which will be comparable to other current fuels such as natural gas. It is not an easy task because natural gas is formed by Mother Nature over several hundred thousand years. It is readily available and there is no manufacturing cost except processing cost. We are used to free energy from Mother Nature. This is the crux of the issue.

Hydrogen is the most abundantly available element on earth; yet it is not available in a free form. It is available as a compound, such as, joined with oxygen forming   water H2O molecule; or joined with Carbon forming Methane CH4 molecule.This Hydrogen should be separated in a free form, and this separation requires energy. How can coal, which is just a Carbon, generate Hydrogen?  It requires an addition of water in the form of steam.  When coal is gasified with air and steam, a mixture of Hydrogen and Carbon dioxide is generated, known as Syngas (synthesis gas).

2C + H2O+O2  ———  2H2 +2 CO2

The syngas is separated into Hydrogen and carbon dioxide using various methods using their difference in densities. The Hydrogen can be stored under pressure for further use. Research work is now under way to capture carbon dioxide for sequestering. Carbon sequestration is a method of capturing carbon dioxide and storing it in a place where it cannot enter the atmosphere. But the technical feasibility and economic viability of such a system is yet to be established.

Carbon sequestration is a new concept and the cost of sequestration can potentially increase the cost of energy derived from Hydrogen despite the fact, Hydrogen has energy content five times more the carbon. However, there is no quick fix for our energy problems, and we have to reconcile to the energy cost will increase in the future but eventually cut the greenhouse emissions. These developed countries should at least show to the rest of the world, how they plan to cut their emissions and their action plans; such disclosure should be subject to inspection by UN panel. In the absence of any concrete mechanism, it will be impossible to stop the global warming in the stipulated time frame considering the fact that a number of coal/oil/gas-fired power plants are already under implementation.